1
as in unused
not having acquired a habit or tolerance
pampered youngsters who were unaccustomed to such hard work
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2
as in unfamiliar
not known or experienced before
the unaccustomed friendliness of my relatives after I won the lottery
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3
as in unusual
noticeably different from what is generally found or experienced
unaccustomed styles of cooking that the tourists had to be persuaded to try
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Merriam-Webster unabridged
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